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What Are The Different Grades of Calcium Carbonate?

Introduction to Precipitated Calcium Carbonate (PCC)

Precipitated Calcium Carbonate (PCC) is a refined, synthetic form of calcium carbonate (CaCO₃) produced by chemically reacting calcium hydroxide with carbon dioxide. Unlike its natural counterpart—ground calcium carbonate (GCC)—PCC is characterized by high purity, controlled particle size, and specific morphology. These qualities make it a highly versatile material across various industries, including paper manufacturing, plastics, pharmaceuticals, food, and construction. However, not all PCC is created equal. To meet specific application requirements, PCC is available in a range of grades, each tailored with distinct physical and chemical properties. Understanding these differences is crucial for selecting the right type for optimal performance and efficiency in end-use applications.


What Are the Different Grades of Precipitated Calcium Carbonate?

The grades of PCC differ primarily in terms of particle size, morphology, surface area, brightness, and surface treatment. These variations influence the behavior of PCC in different materials and applications. The main PCC grades can be categorized as follows:

1. Ultrafine Grade PCC

Ultrafine PCC is engineered with extremely small particle sizes, often in the submicron range. Its high surface area enhances binding strength and opacity, which is especially valued in high-grade paper coatings, paints, and printing inks.

  • Particle Size: < 1 μm

  • Application: High-quality printing paper, paints, and coatings

  • Advantages: Excellent brightness, improved opacity, increased viscosity control

Ultrafine PCC enables the production of ultra-smooth surfaces in coated paper and delivers better light scattering for higher brightness levels. In the plastic industry, its fine dispersion helps achieve enhanced mechanical properties and optical clarity.

2. Coated PCC

Coated PCC involves surface modification—often with fatty acids or coupling agents—to enhance its compatibility with hydrophobic matrices like polymers. The coating acts as a coupling bridge between PCC and the host material.

  • Surface Treatment: Typically stearic acid

  • Application: Plastics (e.g., PVC, polyethylene), rubber, adhesives

  • Advantages: Improved dispersion, enhanced impact strength, moisture resistance

This grade significantly boosts the end-use properties of thermoplastics by reducing water absorption and increasing dimensional stability. Coated PCC is also a cost-effective filler, often replacing more expensive resin in formulations.

Calcium Carbonate

3. Pharmaceutical and Food Grade PCC

This grade meets strict standards for purity and safety, making it suitable for ingestion and use in sensitive applications. Pharmaceutical PCC is commonly used as a calcium supplement and an excipient in tablets.

  • Compliance: USP, FCC, and E170 (EU food additive)

  • Application: Calcium supplements, antacids, food fortification, dental care

  • Advantages: High bioavailability, neutral taste, fine mouthfeel

Purity is paramount for this grade, and production is tightly controlled to avoid heavy metal contamination. Its high chemical consistency also ensures reproducibility in pharmaceutical formulations.

4. Technical Grade PCC

Technical-grade PCC is widely used in industrial applications that do not demand high purity but require effective filler or functional properties.

  • Application: Construction materials, paints, ceramics, rubber, and sealants

  • Advantages: Cost-effective, moderate particle size, general-purpose performance

Though not suitable for sensitive applications, technical PCC is essential in improving strength and processability in construction products such as mortar and sealants. It also offers improved rheological behavior and cost reduction in industrial coatings.

5. Cosmetic Grade PCC

This ultra-pure grade is used in personal care and cosmetic formulations where safety, appearance, and sensory characteristics are critical.

  • Application: Toothpastes, face powders, body lotions

  • Advantages: Whitening effect, fine texture, safe for dermal use

It often serves as a mild abrasive and whitening agent in oral care products. Its smoothness and oil absorption properties also make it an ideal component in powders and creams.

6. Nano PCC

Nano PCC is a relatively new development, characterized by its nano-scale particle size that imparts unique surface chemistry and reactivity.

  • Particle Size: < 100 nm

  • Application: High-tech applications, including biomedical, specialty coatings, and advanced plastics

  • Advantages: Exceptional dispersion, high reactivity, novel functional properties

Nano PCC is particularly promising in advanced composites, offering superior reinforcement at low loading levels. It’s also being explored in controlled drug release and biocompatible materials.

Calcium Carbonate

Comparison Table: Grades of Precipitated Calcium Carbonate

Grade Key Features Common Applications Particle Size Range
Ultrafine PCC High brightness, fine particles Paper coating, paints < 1 μm
Coated PCC Surface modified for better bonding Plastics, rubber 0.5–2 μm
Pharmaceutical/Food PCC High purity, bioavailability Tablets, supplements, food 0.5–3 μm
Technical PCC Cost-efficient, functional Construction, ceramics 2–10 μm
Cosmetic PCC Smooth texture, safe for skin contact Toothpaste, powders 0.5–2 μm
Nano PCC Nano-scale, high surface reactivity Biomedical, specialty coatings < 100 nm


FAQs about Precipitated Calcium Carbonate Grades

Is there a difference between PCC and GCC?

Yes, PCC is synthetically produced under controlled conditions, resulting in consistent particle size, shape, and purity. Ground Calcium Carbonate (GCC) is obtained by mechanically crushing natural limestone, which can lead to irregular shapes and impurities.

Can different PCC grades be blended for custom applications?

Absolutely. Manufacturers often blend multiple PCC grades to tailor properties like viscosity, opacity, or reinforcement in a cost-effective way. This allows customized formulations for specific end-use requirements.

How do you choose the right PCC grade?

The selection depends on your application needs:

  • For paper and coatings: go for ultrafine PCC.

  • For plastics and rubber: coated PCC works best.

  • For consumables: pharmaceutical or food-grade PCC is mandatory.

  • For general industrial use: technical grade is sufficient.

Consulting with a materials specialist can help identify the best fit.


Conclusion

Precipitated Calcium Carbonate is far more than a simple white powder—it is a high-performance, customizable additive available in various grades to suit the demands of diverse industries. From enhancing brightness in premium paper to improving strength and safety in medical tablets, each grade of PCC brings unique properties and benefits. Whether you are seeking cost efficiency, high purity, or specialized functionality, there is a PCC grade tailored to your specific needs. As industries continue to push boundaries, innovations like Nano PCC are paving the way for next-generation materials with remarkable versatility.


As a leading supplier of calcifiers in China, we rely on a professional team to provide comprehensive support to our customers. We work closely with our partners to help our customers achieve more.

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